Answer by Evan Carroll for How can I validate an email address using a regular expression?

This regex is from Perl's Email::Valid library. I believe it to be the most accurate, and it matches all 822. And, it is based on the regular expression in the O'Reilly book:

Regular expression built using Jeffrey Friedl's example inMastering Regular Expressions (http://www.ora.com/catalog/regexp/).

$RFC822PAT = <<'EOF';[\040\t]*(?:\([^\\\x80-\xff\n\015()]*(?:(?:\\[^\x80-\xff]|\([^\\\x80-\xff\n\015()]*(?:\\[^\x80-\xff][^\\\x80-\xff\n\015()]*)*\))[^\\\x80-\xff\n\015()]*)*\)[\040\t]*)*(?:(?:[^(\040)<>@,;:".\\\[\]\000-\037\x80-\xff]+(?![^(\040)<>@,;:".\\\[\]\000-\037\x80-\xff])|"[^\\\x80-\xff\n\015"]*(?:\\[^\x80-\xff][^\\\x80-\xff\n\015"]*)*")[\040\t]*(?:\([^\\\x80-\xff\n\015()]*(?:(?:\\[^\x80-\xff]|\([^\\\x80-\xff\n\015()]*(?:\\[^\x80-\xff][^\\\x80-\xff\n\015()]*)*\))[^\\\x80-\xff\n\015()]*)*\)[\040\t]*)*(?:\.[\040\t]*(?:\([^\\\x80-\xff\n\015()]*(?:(?:\\[^\x80-\xff]|\([^\\\x80-\xff\n\015()]*(?:\\[^\x80-\xff][^\\\x80-\xff\n\015()]*)*\))[^\\\x80-\xff\n\015()]*)*\)[\040\t]*)*(?:[^(\040)<>@,;:".\\\[\]\000-\037\x80-\xff]+(?![^(\040)<>@,;:".\\\[\]\000-\037\x80-\xff])|"[^\\\x80-\xff\n\015"]*(?:\\[^\x80-\xff][^\\\x80-\xff\n\015"]*)*")[\040\t]*(?:\([^\\\x80-\xff\n\015()]*(?:(?:\\[^\x80-\xff]|\([^\\\x80-\xff\n\015()]*(?:\\[^\x80-\xff][^\\\x80-\xff\n\015()]*)*\))[^\\\x80-\xff\n\015()]*)*\)[\040\t]*)*)*@[\040\t]*(?:\([^\\\x80-\xff\n\015()]*(?:(?:\\[^\x80-\xff]|\([^\\\x80-\xff\n\015()]*(?:\\[^\x80-\xff][^\\\x80-\xff\n\015()]*)*\))[^\\\x80-\xff\n\015()]*)*\)[\040\t]*)*(?:[^(\040)<>@,;:".\\\[\]\000-\037\x80-\xff]+(?![^(\040)<>@,;:".\\\[\]\000-\037\x80-\xff])|\[(?:[^\\\x80-\xff\n\015\[\]]|\\[^\x80-\xff])*\])[\040\t]*(?:\([^\\\x80-\xff\n\015()]*(?:(?:\\[^\x80-\xff]|\([^\\\x80-\xff\n\015()]*(?:\\[^\x80-\xff][^\\\x80-\xff\n\015()]*)*\))[^\\\x80-\xff\n\015()]*)*\)[\040\t]*)*(?:\.[\040\t]*(?:\([^\\\x80-\xff\n\015()]*(?:(?:\\[^\x80-\xff]|\([^\\\x80-\xff\n\015()]*(?:\\[^\x80-\xff][^\\\x80-\xff\n\015()]*)*\))[^\\\x80-\xff\n\015()]*)*\)[\040\t]*)*(?:[^(\040)<>@,;:".\\\[\]\000-\037\x80-\xff]+(?![^(\040)<>@,;:".\\\[\]\000-\037\x80-\xff])|\[(?:[^\\\x80-\xff\n\015\[\]]|\\[^\x80-\xff])*\])[\040\t]*(?:\([^\\\x80-\xff\n\015()]*(?:(?:\\[^\x80-\xff]|\([^\\\x80-\xff\n\015()]*(?:\\[^\x80-\xff][^\\\x80-\xff\n\015()]*)*\))[^\\\x80-\xff\n\015()]*)*\)[\040\t]*)*)*|(?:[^(\040)<>@,;:".\\\[\]\000-\037\x80-\xff]+(?![^(\040)<>@,;:".\\\[\]\000-\037\x80-\xff])|"[^\\\x80-\xff\n\015"]*(?:\\[^\x80-\xff][^\\\x80-\xff\n\015"]*)*")[^()<>@,;:".\\\[\]\x80-\xff\000-\010\012-\037]*(?:(?:\([^\\\x80-\xff\n\015()]*(?:(?:\\[^\x80-\xff]|\([^\\\x80-\xff\n\015()]*(?:\\[^\x80-\xff][^\\\x80-\xff\n\015()]*)*\))[^\\\x80-\xff\n\015()]*)*\)|"[^\\\x80-\xff\n\015"]*(?:\\[^\x80-\xff][^\\\x80-\xff\n\015"]*)*")[^()<>@,;:".\\\[\]\x80-\xff\000-\010\012-\037]*)*<[\040\t]*(?:\([^\\\x80-\xff\n\015()]*(?:(?:\\[^\x80-\xff]|\([^\\\x80-\xff\n\015()]*(?:\\[^\x80-\xff][^\\\x80-\xff\n\015()]*)*\))[^\\\x80-\xff\n\015()]*)*\)[\040\t]*)*(?:@[\040\t]*(?:\([^\\\x80-\xff\n\015()]*(?:(?:\\[^\x80-\xff]|\([^\\\x80-\xff\n\015()]*(?:\\[^\x80-\xff][^\\\x80-\xff\n\015()]*)*\))[^\\\x80-\xff\n\015()]*)*\)[\040\t]*)*(?:[^(\040)<>@,;:".\\\[\]\000-\037\x80-\xff]+(?![^(\040)<>@,;:".\\\[\]\000-\037\x80-\xff])|\[(?:[^\\\x80-\xff\n\015\[\]]|\\[^\x80-\xff])*\])[\040\t]*(?:\([^\\\x80-\xff\n\015()]*(?:(?:\\[^\x80-\xff]|\([^\\\x80-\xff\n\015()]*(?:\\[^\x80-\xff][^\\\x80-\xff\n\015()]*)*\))[^\\\x80-\xff\n\015()]*)*\)[\040\t]*)*(?:\.[\040\t]*(?:\([^\\\x80-\xff\n\015()]*(?:(?:\\[^\x80-\xff]|\([^\\\x80-\xff\n\015()]*(?:\\[^\x80-\xff][^\\\x80-\xff\n\015()]*)*\))[^\\\x80-\xff\n\015()]*)*\)[\040\t]*)*(?:[^(\040)<>@,;:".\\\[\]\000-\037\x80-\xff]+(?![^(\040)<>@,;:".\\\[\]\000-\037\x80-\xff])|\[(?:[^\\\x80-\xff\n\015\[\]]|\\[^\x80-\xff])*\])[\040\t]*(?:\([^\\\x80-\xff\n\015()]*(?:(?:\\[^\x80-\xff]|\([^\\\x80-\xff\n\015()]*(?:\\[^\x80-\xff][^\\\x80-\xff\n\015()]*)*\))[^\\\x80-\xff\n\015()]*)*\)[\040\t]*)*)*(?:,[\040\t]*(?:\([^\\\x80-\xff\n\015()]*(?:(?:\\[^\x80-\xff]|\([^\\\x80-\xff\n\015()]*(?:\\[^\x80-\xff][^\\\x80-\xff\n\015()]*)*\))[^\\\x80-\xff\n\015()]*)*\)[\040\t]*)*@[\040\t]*(?:\([^\\\x80-\xff\n\015()]*(?:(?:\\[^\x80-\xff]|\([^\\\x80-\xff\n\015()]*(?:\\[^\x80-\xff][^\\\x80-\xff\n\015()]*)*\))[^\\\x80-\xff\n\015()]*)*\)[\040\t]*)*(?:[^(\040)<>@,;:".\\\[\]\000-\037\x80-\xff]+(?![^(\040)<>@,;:".\\\[\]\000-\037\x80-\xff])|\[(?:[^\\\x80-\xff\n\015\[\]]|\\[^\x80-\xff])*\])[\040\t]*(?:\([^\\\x80-\xff\n\015()]*(?:(?:\\[^\x80-\xff]|\([^\\\x80-\xff\n\015()]*(?:\\[^\x80-\xff][^\\\x80-\xff\n\015()]*)*\))[^\\\x80-\xff\n\015()]*)*\)[\040\t]*)*(?:\.[\040\t]*(?:\([^\\\x80-\xff\n\015()]*(?:(?:\\[^\x80-\xff]|\([^\\\x80-\xff\n\015()]*(?:\\[^\x80-\xff][^\\\x80-\xff\n\015()]*)*\))[^\\\x80-\xff\n\015()]*)*\)[\040\t]*)*(?:[^(\040)<>@,;:".\\\[\]\000-\037\x80-\xff]+(?![^(\040)<>@,;:".\\\[\]\000-\037\x80-\xff])|\[(?:[^\\\x80-\xff\n\015\[\]]|\\[^\x80-\xff])*\])[\040\t]*(?:\([^\\\x80-\xff\n\015()]*(?:(?:\\[^\x80-\xff]|\([^\\\x80-\xff\n\015()]*(?:\\[^\x80-\xff][^\\\x80-\xff\n\015()]*)*\))[^\\\x80-\xff\n\015()]*)*\)[\040\t]*)*)*)*:[\040\t]*(?:\([^\\\x80-\xff\n\015()]*(?:(?:\\[^\x80-\xff]|\([^\\\x80-\xff\n\015()]*(?:\\[^\x80-\xff][^\\\x80-\xff\n\015()]*)*\))[^\\\x80-\xff\n\015()]*)*\)[\040\t]*)*)?(?:[^(\040)<>@,;:".\\\[\]\000-\037\x80-\xff]+(?![^(\040)<>@,;:".\\\[\]\000-\037\x80-\xff])|"[^\\\x80-\xff\n\015"]*(?:\\[^\x80-\xff][^\\\x80-\xff\n\015"]*)*")[\040\t]*(?:\([^\\\x80-\xff\n\015()]*(?:(?:\\[^\x80-\xff]|\([^\\\x80-\xff\n\015()]*(?:\\[^\x80-\xff][^\\\x80-\xff\n\015()]*)*\))[^\\\x80-\xff\n\015()]*)*\)[\040\t]*)*(?:\.[\040\t]*(?:\([^\\\x80-\xff\n\015()]*(?:(?:\\[^\x80-\xff]|\([^\\\x80-\xff\n\015()]*(?:\\[^\x80-\xff][^\\\x80-\xff\n\015()]*)*\))[^\\\x80-\xff\n\015()]*)*\)[\040\t]*)*(?:[^(\040)<>@,;:".\\\[\]\000-\037\x80-\xff]+(?![^(\040)<>@,;:".\\\[\]\000-\037\x80-\xff])|"[^\\\x80-\xff\n\015"]*(?:\\[^\x80-\xff][^\\\x80-\xff\n\015"]*)*")[\040\t]*(?:\([^\\\x80-\xff\n\015()]*(?:(?:\\[^\x80-\xff]|\([^\\\x80-\xff\n\015()]*(?:\\[^\x80-\xff][^\\\x80-\xff\n\015()]*)*\))[^\\\x80-\xff\n\015()]*)*\)[\040\t]*)*)*@[\040\t]*(?:\([^\\\x80-\xff\n\015()]*(?:(?:\\[^\x80-\xff]|\([^\\\x80-\xff\n\015()]*(?:\\[^\x80-\xff][^\\\x80-\xff\n\015()]*)*\))[^\\\x80-\xff\n\015()]*)*\)[\040\t]*)*(?:[^(\040)<>@,;:".\\\[\]\000-\037\x80-\xff]+(?![^(\040)<>@,;:".\\\[\]\000-\037\x80-\xff])|\[(?:[^\\\x80-\xff\n\015\[\]]|\\[^\x80-\xff])*\])[\040\t]*(?:\([^\\\x80-\xff\n\015()]*(?:(?:\\[^\x80-\xff]|\([^\\\x80-\xff\n\015()]*(?:\\[^\x80-\xff][^\\\x80-\xff\n\015()]*)*\))[^\\\x80-\xff\n\015()]*)*\)[\040\t]*)*(?:\.[\040\t]*(?:\([^\\\x80-\xff\n\015()]*(?:(?:\\[^\x80-\xff]|\([^\\\x80-\xff\n\015()]*(?:\\[^\x80-\xff][^\\\x80-\xff\n\015()]*)*\))[^\\\x80-\xff\n\015()]*)*\)[\040\t]*)*(?:[^(\040)<>@,;:".\\\[\]\000-\037\x80-\xff]+(?![^(\040)<>@,;:".\\\[\]\000-\037\x80-\xff])|\[(?:[^\\\x80-\xff\n\015\[\]]|\\[^\x80-\xff])*\])[\040\t]*(?:\([^\\\x80-\xff\n\015()]*(?:(?:\\[^\x80-\xff]|\([^\\\x80-\xff\n\015()]*(?:\\[^\x80-\xff][^\\\x80-\xff\n\015()]*)*\))[^\\\x80-\xff\n\015()]*)*\)[\040\t]*)*)*>)EOF